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12 Apr 2010

Get the Full Picture of Stainless steel seamless pipe thermal Imaging

A thermocouple was installed in a Stainless steel seamless pipe line for monitoring the temperature of the fluid. Because the piping was all stainless steel, the material surface was too reflective to directly observe the fluid level with the thermal imager. So, to improve emissivity enough to allow camera use, the engineer applied some black electrical tape around the area of the pipe where the thermocouple was installed. The thermal imager revealed that the pipe was less than one-third filled with fluid. The thermocouple was barely making contact with the fluid, resulting in erroneous temperature measurements. A vapor lock had produced the unwanted headspace.

A thermal imager may improve your monitoring and troubleshooting of equipment and products. The infrared (IR) camera can supplement or supplant traditional techniques, and provide insights about material storage, equipment heat loss, product moisture content and more.

For instance, plants normally use level indicators to monitor how much material is inside a tank. Yet, many sites increasingly are turning to IR cameras to do the same thing. They want to avoid false indications from level gauges — and the resulting risks of either running out of product or, worse, overfilling a tank that was supposed to be empty. As former President Reagan was noted for saying: “Trust, but verify.”

Typical thermal images show the contents of the container and give quantifiable verification of the material inside. Users, by applying their knowledge of materials and physics to the thermal differences they see with an imager, can deduce the level of fluid in a tank. Figure 1 clearly shows the liquid level because the tank contains two different materials: liquid and air in the headspace.

Because of that human deductive element, the meaningfulness of the examination depends upon the person’s knowledge and the type of result desired.

Thermal cycling

Tanks located outside undergo thermal cycling. During daylight, they and their contents absorb heat from the sun and the air, as well as from whatever processing might be taking place. During the night, they give up heat to the surrounding air. This thermal cycle and the different thermal capacities of the materials involved affect how accurately a thermal imager can measure product level.

Uninsulated tanks such as the one shown are highly thermally conductive. As night falls, the headspace begins to cool quickly while the liquid volume cools much more slowly. That makes the thermal gradient between the liquid and headspace readily apparent through a thermal imager. Typically the thermal difference is at its maximum two times a day — once in the morning and once in the evening.

At other times, it may not be possible to clearly identify the liquid level with the thermal imager because the liquid and the air in the headspace may approach the same temperature. Reflections from the sunlight during daylight also can make it difficult to observe thermal differences.

Of course, tanks hold materials other than liquids. Dry bulk materials tend to pile up against the sides and have very uneven levels. Thermal imagers enable you to see these irregularities (Figure 2). Also, many liquids contain particulates that may settle out inside the tank, forming a layer of sediment. This layer generally has different thermal properties than the liquid and, so, often can be identified by imaging.

Understanding what the tank is constructed of is important. Many tanks have low-emissivity shiny metal surfaces or insulated walls that make it difficult or impossible to observe internal thermal differences. Being aware of such factors is crucial when evaluating what a thermal imager appears to be telling you.

Use caution and apply knowledge!

For instance, look at the reactor image (Figure 3). The color temperature bar indicates that dark blue is approximately 95?F and the red at the top of the scale is more than 200?F. Notice the dark blue, apparently cool, band where the lid sits on the vessel. What we really are seeing is a very low emissivity ring of stainless steel around the top of this otherwise painted vessel. The painted portion has a much higher emissivity. The bare stainless steel actually is at the same temperature as the painted portions it contacts <em dash>—<em dash>more than 160?F, hot enough to seriously burn skin.

It is fairly obvious to use a camera to examine furnaces and ovens for heat loss. However, thermography also can offer insights for cooling equipment. For instance, a new process freezer for removing heat from cooked meat patties exhibited numerous areas of condensation on its exterior surface, indicating voids in the insulation system in the walls. The manufacturer drilled holes in the metal sidewalls of the freezer where the condensation was located, trying without success to find the voids. The exterior freezer walls were polished Stainless steel seamless pipe which is very highly reflective. The thermographer dried the areas of condensation, placed black tape over them, and then used the camera to pinpoint the coldest spot. He was able to drill a 2-in. hole at the exact location of the insulation void.

9 Apr 2010

What is the Difference Between 304 and 316 stainless steel pipe

The main difference between 304 and 316 stainless steel pipe is that 316 contains 2%-3% molybdenum and 304 has no molybdenum. The "moly" is added to improve the corrosion resistance to chlorides (like sea water). So, while 316 stainless steel pipe is generally considered more corrosion resistant than 304, depending on the nature of the corrosive media the corrosion rates of 304 and 316 could be similar.

Generally, SS 304/304L is assumed to be corrosion-resistant material. But when we come to Piping Specs with SS 304/304L MOC, its value is taken as 0.063 inches -- same for SS316/316L . Please explain.

We have a plant that produces fertilizer. In one section we mix 40% phosphoric acid and 98% sulfuric acid together in a ratio of 75-80 : 25-20 phosphoric acid:sulfuric acid. After that the mixture is cooled to a temperature of 80 degrees C. What is the best material of construction for transfer piping? The existing material, 304 stainless steel pipe, shows problems at the welds.

From a materials of construction perspective, this is a tricky mixture to deal with, especially at 80 degrees C and higher. Phosphoric acid is less corrosive than sulfuric acid. Pure phosphoric acid has no oxidizing power but commercial phosphoric acid contains impurities such as fluorides and chlorides that can significantly increase its corrosivity. The corrosivity of sulfuric acid depends on many factors including temperature, concentration, the presence of oxidizing or reducing impurities, velocity effects, and solids in suspension.

It is usually not wise to select materials of construction for sulfuric acid handling equipment based only on published corrosion data since corrosion by sulfuric acid is a complex phenomenon. Small differences in impurities, velocity, or concentration can significantly impact the corrosion rate. Halides generally increase corrosion while aeration or the presence of oxidizing agents usually increases the corrosion rate of non-ferrous materials and reduces the corrosion rates of stainless steel pipe alloys. I strongly recommend laboratory corrosion studies be run on your specific stream as a part of your material of construction selection process.

I have a large storage tank of 93% sulfuric acid. I am having excessive corrosion of the top of the 4-inch carbon steel outlet pipe. I am thinking of replacing the outlet pipe with Schedule 120 carbon steel pipe. Is there any more resistant material, insert, or coating you could recommend for increased life?

Carbon steels are only acceptable for 93% sulfuric acid when fluid velocity is low (< 3 ft/sec). For 4-inch diameter piping or less with velocities up to 5.9 ft/sec, 316L stainless steel pipe is a good choice. For velocities higher than 5.9 ft/sec, Alloy 20Cb-3 (UNS N08020) has been used successfully. For additional information, consult NACE Recommended Practice RP-0391 "Materials for the Handling and Storage of Commercial Concentrated (90 to 100%) Sulfuric Acid at Ambient Temperatures."

In your question, you said you are experiencing problems with 304 stainless steel pipe at the welds. If this is the case, you might consider moving to 304L stainless steel pipe. Low carbon versions of austenitic Stainless steel seamless pipe like 304L are designed to eliminate problems associated with carbide precipitation and chromium depletion at welds. If 304L doesn't work, try gradually moving up to a higher alloy. Possible candidate materials in order of generally increasing corrosion resistance are: 316L stainless steel pipe, 20-type alloys like 20Cb-3, higher chromium Fe-Ni-Mo alloys like Alloy 31, and nickel-base molybdenum-chromium alloys like C-276.

7 Apr 2010

Get Stainless steel pipe Specifications Right in the Beginning

My company couldn’t see all the fuss. We had been hired by Bechtel as a subcontractor for the ill-fated Goro project to refine nickel ore in New Caledonia. Bechtel wanted us to match its pipe specifications. To us, this was just another symptom of a bloated project. We used to joke that Bechtel had two engineers for toilets: one for the men’s room and one for the women’s room. Looking back, Bechtel’s approach made sense: get the Stainless steel pipe specifications right or live with a project fraught with headaches — never mind other minor issues, i.e., safety, reliability and profitability.

The first decision in establishing a pipe standard is choosing whether it will be based on function or condition. A function-based specification would be something such as a sewer pipe or vent duct. A condition-based specification would discriminate between sewer pipe for corrosive versus sanitary service. Usually, a condition-based specification is best.

Collecting information is the next step. Pipe specifications often are presented in tables kept in massive volumes. What’s missing is supporting information explaining the basis for decisions like the choice of type 316 stainless steel over type 304L, or selection of Inconel 601 instead of Inconel 600. This omission in company records almost justifies the reluctance I’ve witnessed to challenge pipe specifications.

Once information is collected, you should budget time for careful analysis by a consultant. The idea is to look for discrepancies between the pipe specifications and for areas of improvement. For example, Trevor Kletz, in his book “Process Plants: A Handbook for Inherently Safer Design,” suggests eplacing fiber gaskets with spiral-wound gaskets because their leak rate is lower.

With the analysis complete, it’s time for a meeting. Bring together maintenance staff, project engineers, vendors and contractors to pencil in the details of the new pipe specifications. Leave detailed discussion of any contentious points to follow-up meetings. Rely on empirical data!

Sadly, plants seldom use one important source of empirical data — the corrosion coupon, which is a welded strip of metal designed to be inserted into a process. Instead, they allow analysis of the effects of corrosion on parent metal and welds. Coupons, which also can be used for gasket materials in some applications, provide real data well beyond those found in textbooks and from laboratory analysis, which seems artificial by comparison. The downside is exposure time; material evaluation takes months. But, believe me, it’s worth it.

Consider what happened on another project. We had to handle a feed stream of aluminum chloride added to a stream containing wet chlorine gas and vaporized titanium tetrachloride. A world-renowned valve material expert claimed that zirconium oxide would survive our process. Being prudent, I suggested coupons but was overruled because of time constraints. The expert was dead-wrong! What we saw was quickly dubbed “the jawbreaker effect” by our operators. Over about six weeks, the balls in our ball valves shrunk, flaking away from thermal shock. Coupons would have saved us more than $1 million a/year in downtime during the next few years and justified a ball made of a more expensive ceramic.

With all basic facts now in hand, it’s time to schedule follow-up meetings to review the draft pipe specifications. The best format for these specifications consists of a single page summary followed by details, exceptions and references. The details should include gaskets, valves, fasteners (e.g., bolts), special fittings, construction aspects such as weld inspection and paint preparation, etc. If possible, review the specifications with your mechanics. They may want to pass on their wisdom on construction details.

Exceptions may exist, and where they do, they must be clarified and documented. Sometimes exceptions arise because a vendor can’t change a valve specification and an acceptable alternative hasn’t been found yet. In one company, we ordered a PTFE-lined plug valve and modified it to fit an actuator.

Keep the summary table relatively simple. It should include pressure rating; application, i.e., for which chemicals; connections, e.g., threaded or socket-welded; and material of construction. It’s best to isolate the summary table so that it’s compact and usable by those in the field.

References should include the ANSI number and the old pipe specification number it replaced if there is one. Clearly state temperature limits; separately cite test pressures for ambient pressure tests. If you must note vendor information, also try to include acceptable alternatives. Keep your options open with vendors. Saving a little money now on a sole-source contract often isn’t worth the headache later of finding a replacement when a part fails to meet quality standards.

An often-overlooked item is the cross-comparison table, which matches the new specifications against the old ones. This table is crucial for working with old vendors and old inventories.

Stainless steel seamless pipe specifications are one of the keys to safe plant operation. By not keeping them current or allowing them to become confusing or hard to use, you may encourage deviation from good engineering practices. Make specifications simple and easy to follow.

2 Apr 2010

How are different classes of Stainless steel pipe used

The three major classes of Stainless steel pipe are:

Austenitic: Chromium-nickel-iron alloys with 16-26% chromium, 6-22% nickel (Ni), and low carbon content, with non-magnetic properties (if annealed - working it at low temperatures, then heated and cooled). Nickel increases corrosion resistance. Hardenable by cold-working (worked at low temperatures) as well as tempering (heated then cooled). Type 304 (S30400) or "18/8" (18% chromium 8% nickel), is the most commonly used grade or composition.

Martensitic: Chromium-iron alloys with 10.5-17% chromium and carefully controlled carbon content, hardenable by quenching (quickly cooled in water or oil) and tempering (heated then cooled). It has magnetic properties. Commonly used in knives. Martensitic grades are strong and hard, but are brittle and difficult to form and weld. Type 420 (S42000) is a typical example.

Ferritic: Chromium-iron alloys with 17-27% chromium and low carbon content, with magnetic properties. Cooking utensils made of this type contain the higher chromium levels. Type 430 is the most commonly used ferritic.

Two additional classes worth mentioning include Duplex (with austenitic and ferritic structures), and Precipitation Hardening stainless steel, used in certain extreme conditions.The austenitic microstructure is most commonly used for knives and cooking utensils. It is very tough, hardened through a process that consists of heating, cooling and heating. It resists scaling and retains strength at high temperatures.

Both ferritics and austenitics are used in kitchenware and household appliances. Austenitics are preferred in the food industry and beverage equipment due to the superior corrosion resistance and ease of cleaning. Type 301, for example, is an austenitic stainless steel, with 17% chromium, 7% nickel, and .05% carbon, and is widely used for institutional food preparation utensils.

You can easily make do with the lesser quality cookware for most oven use. For stovetop cooking, however, don't skimp on quality; buy only the better ones. Most manufacturers of high quality cookware use stainless steel similar to the Type 304 grade, with thick heat diffusing bottoms. Metals that provide better diffusion of heat, such as copper and aluminum, are attached to the bottom for heat diffusion, to prevent hot spots and uneven cooking.

Low quality cutlery is generally made out of grades like 409 and 430 (ferritic), while the finest Sheffield cutlery uses specially produced 410 and 420 (martensitic) for the knives, and 304 (austenitic) for the spoons and forks. Grades like the 410/420 can be hardened and tempered so that the knife blades will take a sharp edge, whereas the more ductile 304 stainless is easier to work and therefore more suitable for objects that have to undergo numerous shaping, buffing and grinding processes.

The best quality Stainless steel seamless pipe have a high carbon content, and usually have molybdenum and vanadium in their composition.

31 Mar 2010

Some Industrial Stainless steel pipe For Various Applications

Industrial Stainless steel seamless pipe is the broader category used in order to describe materials that transport fluid and solid according to the needs of various industries.

Cylindrical and rigid tube counterparts are favored in energy, civil infrastructure and construction applications. Most industrial pipes are cylindrical in shape with systems that are formed through straight sections in the form of fittings. Steel pipes are included in the list of this industrial product category.

When choosing to buy any type of industrial pipe, including steel pipes, one must be able to look into the wall thickness, metric or English sizes and pipe schedules. The latter is important in the classification of wall thickness construing with the requirements of the American National Standards Institute. Section shapes like oval, square, round or rectangular may also be regarded. To learn more about these products, take a glimpse at the various applications or industries where they are employed.

Water and gas pipelines

Different industrial pipes may be used in the water industry. Water mains, sewerage systems and industrial water lines need these industrial products. Of course, plant piping requires the use of any form of steel pipe. If there is one water industry application where these products are used, that would be under the banner of agriculture and irrigation. In these departments, deep tube wells and casing pipes are to be produced.

Oil industries also need some help from industrial pipes that are made out of steel. There are various forms of pipe lines utilized in order to transmit natural gas as well as manufacture LPG and other forms of non-toxic gases. Different types of piping for oil refinery, crude oil and cross country pipe lines rely upon these pieces too. Different industries making use of steel industrial pipes

In a more specific sense, there is a list of industries that utilizes steel pipes. First on the list are construction industries that purposely use these industrial products for scaffolding and structural reasons. Chemical industries are also included because these industrial pipes are heavily favored especially when conveying chemicals. Automobile industries are not exempted from utilizing these items since they rely on them for purposes of air and water flow systems.

Of course there are still other purposes served by steel pipes. Supply and exhaust piping, tubes for idlers and troughed belt conveyors and cold storage industries are given help by such industrial products. These items are made to construe with all standards set by the industry.

Visit stainlesssteelseamlesspipe.net to read the latest about industrial technology stories covering new kinds of Stainless steel pipe and other NEW industrial products and technologies.

29 Mar 2010

Stainless steel pipe Products

Whether it is Stainless steel pipe, roof sheeting or fencing, South African buyers can easily find whatever Stainless steel products in any size or shape they require.

Stainless steel products can be broadly categorized into long or flat products. Long products are typically used in construction, for example re-enforcing bar (rebar) or pipes, while flat products are most often used in the manufacture of cars, ships and white electric goods such as fridges and washing machines. Stainless steel is used in the manufacture of cutlery and surgical equipment.

As these products are used in such a wide variety of applications, different types of steel are used to comply with different requirements. Depending on the production process, steel can be made stronger, non-corrosive or more flexible.

Hot-rolled steel - steel that is processed while hot - is rougher in appearance than cold-rolled steel and less expensive, but also stronger. High-quality products, such as cars and fridges, are usually made using more expensive cold-rolled products.

Stainless steel is manufactured by adding chromium and nickel, leaving the end product resistant to rust, stains and corrosion.

Galvanised steel products - steel that are covered in a layer of zinc - are also widely used in applications where rust resistance is needed, for example roof sheeting. Aluminized steel - steel covered with aluminium and silicon - is commonly used for heat exchangers in residential ovens, water heaters, fireplaces and baking pans.

With steel products being used in anything from irrigation to security, steel suppliers offer a wide variety of products and value-adding services, allowing buyers to have products rolled, cut, bent or welded to specification.

Some of the available products include Stainless steel seamless pipe, valves, gaskets, nuts and bolts, window sections, construction bars, beams, palisade and wire fencing, and walkway grating.

26 Mar 2010

A Stainless Steel Kitchen Counter Top Or Stainless Steel Backsplash

A Stainless steel seamless pipe kitchen countertop or stainless steel backsplash tend to make a room look more spacious and bright which is why they are well suited for kitchens of any size, especially small ones. Stainless steel complements and matches pretty much any color scheme or kitchen design you may have.

With qualities like corrosion resistance and its durability stainless steel is not only a stylish choice it is also a very practical choice for a kitchen counter top surface. Stainless steel when used for a kitchen counter top or backsplash, whether for just a section or for the entire counter, can give any kitchen a look of upscale sophistication. Of course stainless steel has its pros and cons and it depends on your own personal preferences and lifestyle whether or not it really is the choice for you.

Starting with restaurants and commercial kitchens stainless steel kitchen countertops began to appeal to homeowners, who have chosen it to spice up their kitchen decorating and designs. Stainless steel proved its durability with these original uses and other qualities that are desirable in any kitchen. One is the stain resistance that it offers, it is virtually impossible to stain it, hence its name. For food preparation areas stainless steels anti bacterial qualities also can not be beat, any harmful bacteria can be removed with ease.

Most importantly stainless steel kitchen counter tops won't rust, fade, chip, or stain. They are not only durable, but heat-proof, completely water-proof, and resistant to gouging and denting. Also, a stainless steel countertop is easily serviceable in case deep scratches or dents that are major occur.

The fact is that in todays kitchens there are a lot of metal surfaces exposed on appliances and trim, what better to complement it with than a stainless steel backsplash or counter top. This is one of the reasons why stainless steel as a backsplash or counter top have become so popular, they look so good. It is not cheap however, so If your counter top area is large and you plan to use Stainless steel pipe it can get quite expensive. This is why one cost cutting way of adding the sleekness of a stainless steel countertop to a kitchen, that homeowners choose, is to mix and match stainless steel with different materials or ones that are not quite as expensive. This is very effective with stainless steel backsplashes. As an example some choose a countertop surface theme using using materials like laminate or granite, for instance, and only have the area around the sink or stove done with a stainless steel counter top.

Now on the down side a stainles steel kitchen counter top, when worked on, can be noisy. This can be minimized by purchasing a better grade and higher gauge of stainless steel. The grade is determined by the chromium and nickel content, the higher this content is the higher the grade, home stainless steel counter tops should be fabricated with 304 stainless steel.

The thickness should be a 16 gauge stainless steel which is primarily used for residential stainless steel countertops while lower 14 and 12 gauge are used for industrial applications. It is worth it to buy quality stainless steel. A better grade and higher gauge will not only minimize noise but, also have better stain and corrosion resistance properties.

For all practical reasons and Stainless steel pipe is a practical countertop material choice, when quality is purchased and cared for properly you can bring a long lasting, durable and almost maintenance free contemporary and sophisticed warmth to your kitchen with the addition of a stainless steel backsplash and a stainless steel kitchen counter top.

24 Mar 2010

Stainless Steel Sink Gauge - What it Means and What Gauge is Best For Your Kitchen

Searching for a new kitchen sink for your home can be easy and pain-free if you are well informed. There are several aspects of Stainless steel seamless pipe kitchen sinks that many consumers are not very well educated on, one of which being a sink's gauge.

The gauge of a stainless steel sink indicates the thickness of the metal that is used in its manufacture. It can be measured using a micrometer. The gauge of a sink will vary depending on brand, type, and purpose of the sink. It can be very deceiving to the uninformed consumer who finds a 18g and a 16g sink and assumes it is of better quality and thickness because the number is higher. In truth the lower the number, the thicker the sink.

If you are having granite, marble, or another solid surface countertop installed you will most likely have an undermount sink installed. Undermount sinks range in gauge from 16-20g. The average thickenss in stainless steel undermount kitchen sinks is 18g.

The 18g is widely considered a good thickness for use in a kitchen sink. You should have no bending or dinging over time from an 18g sink. Twenty gauge sinks are usually not used as they are generally regarded as very thin. Obviously, the best choice would be to go with a 16g sink. A 16g sink is going to be the most durable option, and will most likely outlast your kitchen.

Kitchen will minimally have a stove top, sink and oven. Most include a refrigerator with a drink dispenser and a microwave. The larger units can have cabinets for storage. Some units have shelves with baskets. Most of the models have a back that you can place against a wall. Other units are designed to be set out in the room allowing multiple children to play from all sides.

Play kitchen sets have realistic electronic features for the microwave, oven, dishwasher, stove top, phone, and light. A special frying pan, and boiling pot with lid, activate electronic frying and boiling water sounds when used on the stove top.

If you are having laminate or another type of countertop installed you will most likely have a topmount sink installed. Topmount Stainless steel pipe sinks are usually available thinner, and are generally less expensive than undermount sinks. The average topmount sink is 20g, but they can be found ranging 18-22. The same rules apply to topmount sinks, the lower the number, the thicker the steel, and more likely the better the quality of sink.

22 Mar 2010

How to Choose the Right Stainless Steel Food Containers

Stainless steel seamless pipe is a low maintenance, inexpensive, and elegant material that continues to gain recognition, especially in the kitchen. With the high demand lately about ecological awareness and sustainability, choosing stainless steel food containers, such as tiffin boxes is definitely a smart environmental decision.

Find below some practical tips and tricks in selecting the right stainless steel food container:

1. Choose a high-grade stainless steel food container. Since you will be chiefly using these storage pieces for meals, it is highly suggested to go for something that is made from food grade 202 stainless steel, and is 100% BPA-Free (Bisphenol A, a perilous component normally found in plastics). You absolutely don't wish any dangerous toxins to come in contact with your food, and jeopardize your health in the long run.

2. Think about your food storage needs. Select bigger food tins for storing leftovers in your fridge. Smaller ones are perfect for bringing lunch to school, office, and even during those unplanned road trips. Fortunately, most of these earth-friendly food containers can meet both of these requirements.

3. Opt for air-tight and liquid-tight stainless steel lunch bowls or multi-tiered latch tiffin lunch containers for portable meals that include soups, stews, and sauces. For meals with more than one food item, choose something that offers two to four levels to keep your meals conveniently divided, such as latch tiffins. Available in many sizes, these tiffin lunch boxes are durable and watertight.

4. Select one that fits your needs when transporting and reheating foodstuff. There are some that enable you to reheat your meals in the container on the stovetop, in a toaster oven, or an open flame. Nevertheless, remember that all steel and metal products are not microwavable.

5. Know the cleaning instructions for your stainless steel food container if ease of care is crucial to you. Other food containers are safe for dishwashing, while some need hand washing. However, those spill-proof food containers have rubber or silicone seals that may not be dishwasher safe.

6. Pick something sturdy yet stylish. As you will be bringing around your tiffin box at school, work, camping, and picnics, choose a stainless food storage that is built to last a long time. While durability is essential, style is also vital. So find something that also comes with glossy exterior, and cool colors and designs to fit your fashion sense.

If you are determined to care for Mother Nature, it's time to take some action! Get started on your kitchen and give up on those non-biodegradable plastic bags and containers that are very harmful to the environment. Instead, go for reusable, eco-friendly, Stainless steel pipe food containers. Just follow the guidelines above to find a tiffin box ideal for your food storage needs and preferences.

19 Mar 2010

Electron Spectroscopy For Chemical Analysis of Stainless Steel and Nitinol

Many manufacturing processes require the passivation of the material in order to ensure the surface is inert or non-reactive. With Stainless steel seamless pipe, for example, the passivation of the surface helps prevent corrosion or rust.

For Nitinol (a nickel-titanium alloy), the passivation of the materials helps prevent corrosion, as well as aids biocompatibility. The passivation of Nitinol will usually deplete the surface of nickel, which can cause severe allergic reactions in the human body.

For materials including stainless steel and Nitinol, whose passivation layers may be quite thin, surface analysis is one of the few techniques capable of providing a chemical analysis of the layer. One of the most commonly used techniques is electron spectroscopy for chemical analysis (ESCA, also called x-ray photoelectron spectroscopy, XPS).

ESCA has a sampling depth of approximately 30 Angstroms and can provide the chemical composition and thickness of the passivation layer. This technique is also cited by the semiconductor industry in specifications for testing the passivation of stainless steels.

The method utilizes an x-ray beam to excite a solid sample, resulting in the emission of photoelectrons. An energy analysis of these photoelectrons provides both elemental and chemical bonding information about a sample surface. The principal advantage of ESCA is its ability to look at a broad range of materials - including polymers, glasses, fibers, metals, semi-conductors and paper - and identify surface constituents as well as their chemical state.

Electron Spectroscopy for Chemical Analysis of Stainless Steel

The characteristics used to evaluate passivated stainless steel are the chromium-to-iron and the chromium oxide to iron oxide ratios. Both of these ratios, as well as the thickness of the passivation layer, can be measured using ESCA.

Electron Spectroscopy for Chemical Analysis of Nitinol

Nitinol is a shape memory alloy with superelastic properties. However, to be used in medical devices, the alloy must be passivated to prevent corrosion and any possible leaching of nickel into the human body.

ESCA is a useful technique for evaluating the Stainless steel pipe passivated Nitinol surface for the presence or non-presence of nickel and determining the thickness of the passivation layer. Nitinol will usually passivate by forming a titanium dioxide layer on the surface.